# CHM 1046L Chemical Equilibrium Lab Report

CHM 1046LSpring 2023
Pre-Lab for Module 6 (Chemical Equilibrium Part 2)
Equilibrium Worksheet – Finding equilibrium concentrations and finding Kc
❖ Keep in mind that you can only calculate the equilibrium constant from
equilibrium concentrations and vice-versa.
❖ So if the problem only has initial (or non-equilibrium) concentrations, you first
need to calculate the equilibrium concentrations before finding the equilibrium
constant.
❖ Alternatively you can also use the initial (or non-equilibrium) concentrations
and the equilibrium constant to determine equilibrium concentrations.
❖ We can do this because stoichiometry relates the reactants to the products and
we can use this to determine how much products is formed and how much
reactant is lost.
Calculate equilibrium concentrations and the equilibrium constant from given initial
concentrations and the equilibrium concentration of a single reactant or product.
A flask is filled with 2.00 M CO2, which decomposes according to the following reaction
2CO2 (g)  → 2CO (g) + O2 (g)
At the very beginning of the reaction how much CO2 will be present in the flask initially?
At the very beginning of the reaction how much CO and O2 will be present in the flask initially?
Is the reaction currently at equilibrium? Why?
Which direction will the reaction shift to reach equilibrium?
Will reactants be consumed or created? Would that be a + or a -?
Will products be consumed or created? Would that be a + or a -?
In a sentence describe what is happening in the reaction in terms of stoichiometry.
If a change of one mole was represented by x what would be the change of each of the reactants
and products (do not forget the signs).
Change in CO2 =
Change in CO =
Change in O2 =
1
CHM 1046L
Spring 2023
In the table below fill in the blanks based on what you already know
2CO2 (g)  → 2CO (g) + O2 (g)
CO2
CO
O2
Initial concentration (I)
Change in concentration (C)
Equilibrium concentration (E)
Problem
A flask is filled with 2.00 M CO2, which decomposes according to the following reaction
2CO2 (g)  → 2CO (g) + O2 (g)
Find the equilibrium constant of the reaction of the flask contains 0.90 M CO2 at equilibrium.
2
CHM 1046L
Spring 2023
Part 1: Phase 1
The chemical reaction for the formation of the red-orange iron(III) thiocyanate complex ion is
Fe3+ (aq) + SCN (aq) [FeSCN2+] (aq)
What is the source of the Fe3+ ions?
What is the source of the SCN- ions?
The equilibrium constant for this reaction is given by
The stock solution in the stock beaker contains 10.00 mL of 0.1000 M iron(III) nitrate
solution, 10.00 mL of 0.1000 M potassium thiocyanate solution, and 10.00 mL of 0.5000 M
nitric acid solution.
What is the total volume of the stock solution? SHOW YOUR WORK!
How many moles of iron (III) nitrate are present in the stock solution? SHOW YOUR WORK!
How many moles of potassium thiocyanate are present in the stock solution? SHOW YOUR
WORK!
3
CHM 1046L
Spring 2023
Based on the moles of iron (III) nitrate and moles of potassium thiocyanate, how many moles
of iron (III) thiocyanate do you expect to be formed (Hint: think limiting reagent)? We can do
it this time because we have enough of one reagent to force the reaction to completion.
Once you determine the moles of iron (III) thiocyanate formed, determine the concentration of
iron (III) thiocyanate in the final solution. SHOW YOUR WORK!
Part 1: Phase 2
1) What is the concentration of iron (III) thiocyanate in solution 2 that contains 10.00 mL
of stock solution, labeled “Solution 1” (you just calculated the concentration of this
solution in phase 1) and 40.00 mL of nitric acid solution? SHOW YOUR WORK!
2) What is the concentration of iron (III) thiocyanate in solution 3 containing 10.00 mL of
solution 2 (you just calculated the concentration of this solution in phase 2 question
1) and 40.00 mL of nitric acid solution? SHOW YOUR WORK!
4
CHM 1046L
Spring 2023
3) What is the concentration of iron (III) thiocyanate in solution 4 containing 10.00 mL of
solution 3 (you just calculated the concentration of this solution in phase 2 question
2) and 40.00 mL of nitric acid solution? SHOW YOUR WORK!
Which substance did you use as the background blank to calibrate the spectrophotometer?
Part 2
No calculations required.
Part 3
We will only be doing calculations for Solution 1 going forward. You will do the
calculations for Solutions 2 and 3 on your own. That should be relatively easier once
we go through the calculation for Solution 1 here.
Solution 1 calculations
1) Solution 1 contains 10.00 mL of 0.002 M iron (III) nitrate solution, 4.00 mL of
0.002 M potassium thiocyanate solution, and 6.00 mL of 0.05 M nitric acid solution.
a) Calculate the concentration of iron (III) nitrate in the final solution in Solution 1.
SHOW ALL WORK!
b) Calculate the concentration of potassium thiocyanate in the final solution in
Solution 1. SHOW ALL WORK!
5
CHM 1046L
Spring 2023
Summarize the concentration of iron (III) nitrate and concentration of potassium thiocyanate
in Solution 1 from your calculations in questions 1a and 1b above. You can fill in the same
for Solutions 2-3 later after doing the calculations on your own time.
Solution
#
mL of iron
(III) nitrate
mL of
potassium
thiocyanate
mL of
nitric acid
M of iron
(III)
nitrate in
the final
solution
M of
potassium
thiocyanate
in the final
solution
Absorbance
of the
solution
1
2
3
You cannot do the limiting reagent thing here because you do not know that one reagent is
in so much excess like before that the reaction will go to completion. So you must calculate
the concentration of the [FeSCN 2+ ] from the graph you created before.
Is the absorbance value of Solution 1 within the range of values on the graph you created
using the data from Phase 2? So can you use this absorbance value to determine the
concentration of [FeSCN 2+ ] from the graph? (think about the definition of the slope and what
the x and y axis are in this case and how it relates to the Beer-Lambert law).
Doing the calculation to find the equilibrium constant
Consider Solution 1 of Part 3,
What is the concentration of iron (III) nitrate aka iron (Fe 3+ ) ions in this tube?
What is the concentration of potassium thiocyanate aka thiocyanate ions (SCN ) ions in this
tube?
Refer back to the graph produced for the Pre-lab Assignment to solve for [FeSCN 2+ ]
According to Beer and Lambert’s law
A = l C
A = absorbance
 = molar absorptivity
l = optical path length in cm (usually 1 cm is the length of the cuvettes used)
C = concentration
6
CHM 1046L
Spring 2023
The equation of a line is y = mx + b
Where
y = value for the Y axis
x = value of the X axis
m = slope
b = y intercept
When the graph passes through the origin, the y intercept (b) is zero.
So your equation becomes y = mx
What is the y axis in this case?
What is the x axis in this case?
y = mx
A = l C
You can get the value of ( x l) from the slope of the graph and so can use this to find
concentration given the absorption and vice versa.
What is the value of the slope from the graph?
What is the concentration of iron (III) thiocyanate in this tube calculated from the graph?
SHOW ALL WORK!
Making an ICE table
A flask is filled with Fe3+ and SCN-, which decomposes according to the following reaction
Fe3+ (aq) + SCN (aq) [FeSCN2+] (aq)
At the very beginning of the reaction how much Fe3+ will be present in the flask initially? You
did this calculation and put down the value previously.
At the very beginning of the reaction how much SCN- will be present in the flask initially? You
did this calculation and put down the value previously.
7
CHM 1046L
Spring 2023
At the very beginning of the reaction how much [FeSCN2+] will be present in the flask initially?
Think about how much product will be present at the very beginning of the reaction.
Was the reaction at equilibrium when the reaction started? Why?
Which direction will the reaction shift to reach equilibrium?
Will reactants be consumed or created? Would that be a + or a -?
Will products be consumed or created? Would that be a + or a -?
In a sentence describe what is happening in the reaction in terms of stoichiometry.
If a change of one mole was represented by x what would be the change of each of the reactants
and products (do not forget the signs).
Change in Fe3+ =
Change in SCN- =
Change in [FeSCN2+] =
In the table below fill in the blanks based on what you already know
Fe3+ (aq) + SCN (aq) [FeSCN2+] (aq)
Fe3
SCN –
[FeSCN2+]
Initial concentration (I)
Change in concentration (C)
(in terms of x)
Equilibrium concentration (E)
We know the value of x because this is the concentration of [FeSCN2+] which you calculated
from the graph. So you can use this to calculate the value of x and therefore the equilibrium
concentrations of Fe3+ and SCN-. SHOW ALL YOUR WORK!
[Fe3+]eq =
[SCN-]eq =
8
CHM 1046L
Spring 2023
[FeSCN2+]eq =
Now that you have these equilibrium concentrations (values) plug them into the equilibrium
constant expression to calculate the value of Kc. SHOW ALL YOUR WORK!
This is the value of Kc that you found from Solution 1
Do you expect the value of Kc that you will find from Solutions 2-3 to be around this number or
be different from the number you just determined? Why or why not? Justify and explain your
reasoning.
Before you leave the lab, you need to do the same calculation that you did for solution 1
(beginning of Part 3 on page 5. Use this worksheet as a template to do those calculations on
solutions 2 and 3 and calculate an average value of Kc from all the 3 values.
Make sure you show the calculation showing how you determined the average. SHOW ALL
9

Don't use plagiarized sources. Get Your Custom Essay on
CHM 1046L Chemical Equilibrium Lab Report
Just from \$13/Page
Calculate the price
Pages (550 words)
\$0.00
*Price with a welcome 15% discount applied.
Pro tip: If you want to save more money and pay the lowest price, you need to set a more extended deadline.
We know how difficult it is to be a student these days. That's why our prices are one of the most affordable on the market, and there are no hidden fees.

Instead, we offer bonuses, discounts, and free services to make your experience outstanding.
How it works
Receive a 100% original paper that will pass Turnitin from a top essay writing service
step 1
Fill out the order form and provide paper details. You can even attach screenshots or add additional instructions later. If something is not clear or missing, the writer will contact you for clarification.
Pro service tips
How to get the most out of your experience with Writall
One writer throughout the entire course
If you like the writer, you can hire them again. Just copy & paste their ID on the order form ("Preferred Writer's ID" field). This way, your vocabulary will be uniform, and the writer will be aware of your needs.
The same paper from different writers
You can order essay or any other work from two different writers to choose the best one or give another version to a friend. This can be done through the add-on "Same paper from another writer."
Copy of sources used by the writer
Our college essay writers work with ScienceDirect and other databases. They can send you articles or materials used in PDF or through screenshots. Just tick the "Copy of sources" field on the order form.
Testimonials
See why 20k+ students have chosen us as their sole writing assistance provider
Check out the latest reviews and opinions submitted by real customers worldwide and make an informed decision.
Psychology
Greater than anticipated. Thanks for the start.
Customer 454569, November 8th, 2020
Psychology
thank you custom scholars. you are awesome
Customer 454893, January 30th, 2022
English 101
Incredible service and final paper! I couldn't be happier. Thank you so much!
Customer 454867, September 8th, 2021
Social Work and Human Services
Thanks a million!!
Customer 453933, October 7th, 2020
Other
Great writer
Customer 454983, March 14th, 2022
Health Care
Thank you very much :)
Customer 455247, February 6th, 2022
Computer science
Great Job!!
Customer 455111, November 15th, 2021
Social Work and Human Services
,
Customer 453933, October 27th, 2020
Philosophy
i like the customer services and the revision was on time. This is my third time using this website. i would recommend them. Just specify what you want and you will get an A in your paper.
Customer 454429, June 16th, 2020
Other
Amazing writer. Truly the best.
Customer 454983, February 19th, 2022
Communications
I recommend this service they always help. I got an A in this project thanks.
Customer 453877, March 8th, 2021
Economics
Excellent!! Great Work Exactly what I needed!!!!
Customer 455199, December 15th, 2021
11,595
Customer reviews in total
96%
Current satisfaction rate
3 pages
Average paper length
37%
Customers referred by a friend